Journal of Bionic Engineering ›› 2021, Vol. 18 ›› Issue (1): 30-39.doi: /10.1007/s42235-021-0005-3

• • 上一篇    下一篇

In situ Reduction of Silver Nanoparticles on Chitosan Hybrid Copper Phosphate Nanoflowers for Highly Efficient Plasmonic Solar-driven Interfacial Water Evaporation

Mei Zhang1, Wanghuai Xu1, Minfei Li1, Jiaqian Li1, Peng Wang2*, Zuankai Wang1*   

  1. 1. Department of Mechanical Engineering, City University of Hong Kong, Hong Kong, 999077, China
    2. Department of Civil and Environmental Engineering, the Hong Kong Polytechnic University, Hong Kong, 999077, China
  • 收稿日期:2020-08-13 修回日期:2020-09-14 接受日期:2020-10-27 出版日期:2021-01-10 发布日期:2021-02-10
  • 通讯作者: Zuankai Wang, Peng Wang E-mail:zuanwang@cityu.edu.hk, peng1.wang@polyu.edu.hk
  • 作者简介:Mei Zhang1, Wanghuai Xu1, Minfei Li1, Jiaqian Li1, Peng Wang2*, Zuankai Wang1*

In situ Reduction of Silver Nanoparticles on Chitosan Hybrid Copper Phosphate Nanoflowers for Highly Efficient Plasmonic Solar-driven Interfacial Water Evaporation

Mei Zhang1, Wanghuai Xu1, Minfei Li1, Jiaqian Li1, Peng Wang2*, Zuankai Wang1*   

  1. 1. Department of Mechanical Engineering, City University of Hong Kong, Hong Kong, 999077, China
    2. Department of Civil and Environmental Engineering, the Hong Kong Polytechnic University, Hong Kong, 999077, China
  • Received:2020-08-13 Revised:2020-09-14 Accepted:2020-10-27 Online:2021-01-10 Published:2021-02-10
  • Contact: Zuankai Wang, Peng Wang E-mail:zuanwang@cityu.edu.hk, peng1.wang@polyu.edu.hk
  • About author:Mei Zhang1, Wanghuai Xu1, Minfei Li1, Jiaqian Li1, Peng Wang2*, Zuankai Wang1*

摘要: The development of water purification device using solar energy has received tremendous attention. Despite extensive progress, traditional photothermal conversion usually has a high cost and high environmental impact. To overcome this problem, we develop a low cost, durable and environmentally friendly solar evaporator. This bi-layered evaporator is constructed with a thermal insulating polyvinylidene fluoride (PVDF) membrane as a bottom supporting layer and plasmonic silver nanoparticles decorated micro-sized hybrid flower (Ag/MF) as a top light-to-heat conversion layer. Compared with the sample with a flat silver film, the two-tier Ag/MF has a plasmonic enrichment property and high efficiency in converting the solar light to heat as each flower can generate a microscale hotspot by enriching the absorbed solar light. On the other hand, the PVDF membrane on the bottom with porous structure not only improves the mechanical stability of the entire structure, but also maintains a stable water supply from the bulk water to the evaporation interface by capillarity and minimizes the thermal conduction. The combination of excellent water evaporation ability, simple operation, and low cost of the production process imparts this type of plasmonic enhanced solar-driven interfacial water evaporator with promising prospects for potable water purification for point-of-use applications.

关键词: bionic, plasmonic, water evaporation, synergistic effect, Ag NPs, hybrid flower

Abstract: The development of water purification device using solar energy has received tremendous attention. Despite extensive progress, traditional photothermal conversion usually has a high cost and high environmental impact. To overcome this problem, we develop a low cost, durable and environmentally friendly solar evaporator. This bi-layered evaporator is constructed with a thermal insulating polyvinylidene fluoride (PVDF) membrane as a bottom supporting layer and plasmonic silver nanoparticles decorated micro-sized hybrid flower (Ag/MF) as a top light-to-heat conversion layer. Compared with the sample with a flat silver film, the two-tier Ag/MF has a plasmonic enrichment property and high efficiency in converting the solar light to heat as each flower can generate a microscale hotspot by enriching the absorbed solar light. On the other hand, the PVDF membrane on the bottom with porous structure not only improves the mechanical stability of the entire structure, but also maintains a stable water supply from the bulk water to the evaporation interface by capillarity and minimizes the thermal conduction. The combination of excellent water evaporation ability, simple operation, and low cost of the production process imparts this type of plasmonic enhanced solar-driven interfacial water evaporator with promising prospects for potable water purification for point-of-use applications.

Key words: bionic, plasmonic, water evaporation, synergistic effect, Ag NPs, hybrid flower