Journal of Bionic Engineering ›› 2020, Vol. 17 ›› Issue (5): 1019-1028.doi: 10.1007/s42235-020-0085-5

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Bio-inspired Superhydrophobic Coating with Low Hydrate Adhesion for Hydrate Mitigation#br#
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Sanbao Dong, Mingzhong Li, Chenwei Liu, Jie Zhang, Gang Chen   

  1. 1. College of Chemistry and Chemical Engineering, Xi’an Shiyou University, Xi’an 710065, China
    2. College of Petroleum Engineering, China University of Petroleum, Qingdao 266580, China
  • 收稿日期:2020-11-20 修回日期:2020-04-12 接受日期:2020-06-20 出版日期:2020-09-10 发布日期:2020-09-04
  • 通讯作者: Sanbao Dong E-mail:dongsanbao@xsyu.edu.cn
  • 作者简介:Sanbao Dong1*, Mingzhong Li2, Chenwei Liu2, Jie Zhang1, Gang Chen1

Bio-inspired Superhydrophobic Coating with Low Hydrate Adhesion for Hydrate Mitigation#br#
#br#

Sanbao Dong, Mingzhong Li, Chenwei Liu, Jie Zhang, Gang Chen   

  1. 1. College of Chemistry and Chemical Engineering, Xi’an Shiyou University, Xi’an 710065, China
    2. College of Petroleum Engineering, China University of Petroleum, Qingdao 266580, China
  • Received:2020-11-20 Revised:2020-04-12 Accepted:2020-06-20 Online:2020-09-10 Published:2020-09-04
  • Contact: Sanbao Dong E-mail:dongsanbao@xsyu.edu.cn
  • About author:Sanbao Dong1*, Mingzhong Li2, Chenwei Liu2, Jie Zhang1, Gang Chen1

摘要: In this paper, we fabricate a biomimetic superhydrophobic coating on an X90 pipeline steel substrate by electrodeposition of copper, hydrothermal treatment to form a copper oxide layer, and subsequent surface modification with Stearic Acid (SA). The coating exhibits static contact angles of water of 160? ± 3.1? in the air and 170.7? ± 2.5? in cyclopentane, indicating the strongly water-repelling nature of the coating. The morphologies of the cyclopentane hydrate formed on steel substrates with and without the superhydrophobic coating are investigated. The results show that the hydrate particle on the coating exhibits spherical morphology and herein the interfacial contact area and adhesion force to the solid surface can be essentially reduced. The adhesion force reduction may be resulted by the decrease in the contact area between the hydrate and the solid surface.

关键词: gas hydrate, cyclopentane, contact angle, bio-inspired coating, superhydrophobic, adhesion

Abstract: In this paper, we fabricate a biomimetic superhydrophobic coating on an X90 pipeline steel substrate by electrodeposition of copper, hydrothermal treatment to form a copper oxide layer, and subsequent surface modification with Stearic Acid (SA). The coating exhibits static contact angles of water of 160? ± 3.1? in the air and 170.7? ± 2.5? in cyclopentane, indicating the strongly water-repelling nature of the coating. The morphologies of the cyclopentane hydrate formed on steel substrates with and without the superhydrophobic coating are investigated. The results show that the hydrate particle on the coating exhibits spherical morphology and herein the interfacial contact area and adhesion force to the solid surface can be essentially reduced. The adhesion force reduction may be resulted by the decrease in the contact area between the hydrate and the solid surface.

Key words: gas hydrate, cyclopentane, contact angle, bio-inspired coating, superhydrophobic, adhesion