Abstract: In this work, we utilized underside of four different plant leaves with different scale of hierarchical surface roughness to fabricate large area self-cleaning antireflective polymer surfaces. A simple and precise two-step soft–lithography replica molding technique was deployed by using polydimethylsiloxane (PDMS) polymer as a replicating material. In the first step, a negative PDMS replica was fab-ricated by using the underside of an original leaf as a template material. In the second step, a positive PDMS replica was fabricated through a negative PDMS replica used as a template. In order to study the non-wetting and light trapping properties, as-replicated polymer surfaces were characterized using Scanning Electron Microscopy (SEM), contact angle goniometer, and UV-Vis spectroscopy. SEM images con-firmed the successful replication of complex hierarchical structures while contact angle measurement studies established retaining high non-wetting properties in polymer replicas. Optical studies suggest near zero reflection in normal mode and less than 5% diffuse reflection when measured using integrated sphere mode. These results have been correlated and explained with the air-liquid fraction and roughness factor as measured using three-dimensional optical profilometer.

Key words: biomimicking, natural leaf, replica molding, non-wetting, light trapping, hierarchical roughness