J4 ›› 2016, Vol. 13 ›› Issue (1): 132-142.doi: 10.1016/S1672-6529(14)60167-0

• 论文 • 上一篇    下一篇

Fabrication and Characterization of Gecko-inspired Dry Adhesion, Superhydrophobicity and Wet Self-cleaning Surfaces

Yongchao Zhang1, Shuxin Qu1, Xiang Cheng1, Xueling Gao1, Xia Guo2   

  1. 1. Key Lab of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China
    2. The Hong Kong Polytechnic University, Department of Rehabilitation Sciences, Kowloon, Hong Kong 999077, China
  • 收稿日期:2015-06-12 修回日期:2015-12-12 出版日期:2016-01-10 发布日期:2016-01-10
  • 通讯作者: Shuxin Qu E-mail:qushuxin@swjtu.edu.cn
  • 作者简介:Yongchao Zhang1, Shuxin Qu1, Xiang Cheng1, Xueling Gao1, Xia Guo2

Fabrication and Characterization of Gecko-inspired Dry Adhesion, Superhydrophobicity and Wet Self-cleaning Surfaces

Yongchao Zhang1, Shuxin Qu1, Xiang Cheng1, Xueling Gao1, Xia Guo2   

  1. 1. Key Lab of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China
    2. The Hong Kong Polytechnic University, Department of Rehabilitation Sciences, Kowloon, Hong Kong 999077, China
  • Received:2015-06-12 Revised:2015-12-12 Online:2016-01-10 Published:2016-01-10
  • Contact: Shuxin Qu E-mail:qushuxin@swjtu.edu.cn
  • About author:Yongchao Zhang1, Shuxin Qu1, Xiang Cheng1, Xueling Gao1, Xia Guo2

摘要:

In this study, gecko-inspired polydimethylsiloxane (PDMS) microfiber surfaces were fabricated by combining Inductively Coupled Plasma (ICP) and micro-mold casting. The effect of roughness and surface energy of counterface on the adhesion of gecko-inspired microfiber surfaces and its superhydrophobicity and wet self-cleaning were studied. The adhesion of gecko-inspired microfiber surfaces depended on the roughness of the counterfaces due to the influences of contact area and interlocking mechanism. SEM images of interfaces between counterfaces with different roughness and gecko-inspired mi-crofiber surfaces revealed the matched and dis-matched contact directly. The gecko-inspired microfiber surface got the larger adhesive force from the higher surface energy counterface, which is consisted with Johnson-Kendall-Roberts (JKR) theory. The smaller dimension and lower duty ratio of microfibers on PDMS resulted in the increasing of Water Contact Angle (WCA) and the decreasing of Sliding Angle (SA) compared to those of smooth PDMS. Particularly, sample P-8-28-20 had the biggest WCA (155?) and SA (7?), which displayed the superhydrophobicity and the best wet self-cleaning efficiency in all samples. The present studies showed that the roughness and surface energy of counterface both affected the adhesion of gecko-inspired microfiber surfaces. The smaller dimension and lower duty ratio of microfibers on PDMS endowed it with the superhydro-phobicity and the wet self-cleaning abilities.

关键词: gecko-inspired microfiber polydimethylsiloxane surfaces, surface properties, counterface, superhydrophobicity, wet self-cleaning

Abstract:

In this study, gecko-inspired polydimethylsiloxane (PDMS) microfiber surfaces were fabricated by combining Inductively Coupled Plasma (ICP) and micro-mold casting. The effect of roughness and surface energy of counterface on the adhesion of gecko-inspired microfiber surfaces and its superhydrophobicity and wet self-cleaning were studied. The adhesion of gecko-inspired microfiber surfaces depended on the roughness of the counterfaces due to the influences of contact area and interlocking mechanism. SEM images of interfaces between counterfaces with different roughness and gecko-inspired mi-crofiber surfaces revealed the matched and dis-matched contact directly. The gecko-inspired microfiber surface got the larger adhesive force from the higher surface energy counterface, which is consisted with Johnson-Kendall-Roberts (JKR) theory. The smaller dimension and lower duty ratio of microfibers on PDMS resulted in the increasing of Water Contact Angle (WCA) and the decreasing of Sliding Angle (SA) compared to those of smooth PDMS. Particularly, sample P-8-28-20 had the biggest WCA (155?) and SA (7?), which displayed the superhydrophobicity and the best wet self-cleaning efficiency in all samples. The present studies showed that the roughness and surface energy of counterface both affected the adhesion of gecko-inspired microfiber surfaces. The smaller dimension and lower duty ratio of microfibers on PDMS endowed it with the superhydro-phobicity and the wet self-cleaning abilities.

Key words: gecko-inspired microfiber polydimethylsiloxane surfaces, surface properties, counterface, superhydrophobicity, wet self-cleaning